Ruthenium(II) carbonyl complexes containing bidentate 2-oxo-1,2-dihydroquinoline-3-carbaldehyde hydrazone ligands as efficient catalysts for catalytic amidation reaction. Lars Ulrik Nordstroem, Henning Vogt, Robert Madsen. Kengo Kataoka, Keiju Wachi, Xiongjie Jin, Kosuke Suzuki, Yusuke Sasano, Yoshiharu Iwabuchi, Jun-ya Hasegawa, Noritaka Mizuno, Kazuya Yamaguchi. Shreyans K. Jain, K. A. Aravinda Kumar, Sandip B. Bharate, Ram A. Vishwakarma. Jyoti Nandi, Matthew Z. Vaughan, Arturo León Sandoval, Joshua M. Paolillo. AIBN-initiated metal free amidation of aldehydes using N-chloroamines. Iodine-Mediated Oxidation of Ynamides: A Facile Access to
Nano rod-shaped and reusable basic Al2O3 catalyst for N-formylation of amines under solvent-free conditions: A novel, practical and convenient ‘NOSE’ approach. Carboxyl activation via silylthioesterification: one-pot, two-step amidation of carboxylic acids catalyzed by non-metal ammonium salts. Somnath Bauri, S. N. R. Donthireddy, Praseetha Mathoor Illam. Direct Observation and Analysis of the Halo-Amino-Nitro Alkane Functional Group. Catalytic Aerobic Dehydrogenative Coupling of Primary Alcohols and Water to Acids Promoted by a Rhodium(I) Amido N-Heterocyclic Carbene Complex. Your Mendeley pairing has expired. This material is available free of charge via the Internet at http://pubs.acs.org. Physical and chemical property of haloalkanes. Organonitrogen Chemicals from Oxygen-Containing Feedstock over Heterogeneous Catalysts. Itzel Mejía-Farfán, Manuel Solís-Hernández, Pedro Navarro-Santos, Claudia A. Contreras-Celedón, Carlos Jesus Cortés-García, Luis Chacón-García. Oxidative amide synthesis directly from alcohols with amines. Akash Mondal, Murugan Subaramanian, Avanashiappan Nandakumar. Senthilkumar Muthaiah, Subhash Chandra Ghosh, Joo-Eun Jee, Cheng Chen, Jian Zhang and Soon Hyeok Hong. 2
Subhash Chandra Ghosh, Senthilkumar Muthaiah, Yao Zhang, Xiangya Xu, Soon Hyeok Hong. One-Pot Synthesis of Carbamoyl Azides Directly from Primary Alcohols and Oxidation of Secondary Alcohols to Ketones Using Iodobenzene Dichloride in Combination with Sodium Azide. Direct Synthesis of Amides by Acceptorless Dehydrogenative Coupling of Benzyl Alcohols and Ammonia Catalyzed by a Manganese Pincer Complex: Unexpected Crucial Role of Base. At equilibrium, PABS-I produced about a 2:3 ratio of 3:1, with an apparent Keq = 2.9 x 103, including both water and (NH4)2SO4 in the expression.11 With AS-I, about 20% of 2 was reconverted to 1 when purified ADIC was incubated with enzyme in the absence of glutamine and ammonium sulfate.10 Despite this hint from nature, the idea that an amine can be hydrolyzed to an alcohol is counterintuitive … ) Bond Functionalization of Arylalkynes through a Nitrogenation Process to Amides. S
B. Watson. How to Name a Compound with Multiple Functional Groups, Reduction of Carbonyl Compounds by Hydride Ion, Reactions of Aldehydes and Ketones with Water, Reactions of Aldehydes and Ketones with Alcohols: Acetals and Hemiacetals, Acetals as Protecting Groups for Aldehydes and Ketones, Imines from Aldehydes and Ketones with Primary Amines, Enamines from Aldehydes and Ketones with Secondary Amines, Reactions of Aldehydes and Ketones with Amines-Practice Problems, Reaction of Aldehydes and Ketones with CN Cyanohydrin Formation, The Wittig Reaction: Examples and Mechanism. Sellappan Selvamurugan, Rangasamy Ramachandran, Govindan Prakash, Periasamy Viswanathamurthi, Jan Grzegorz Malecki, Akira Endo. Foundations of chemistry. One-Pot Synthesis of Symmetrical 1,3-Diarylureas or Substituted Benzamides Directly from Benzylic Primary Alcohols and Effective Oxidation of Secondary Alcohols to Ketones Using Phenyliodine Diacetate in Combination with Sodium Azide. as an inorganic–organic hybrid magnetic nanocatalyst for the synthesis of primary and secondary amides. Hydrogen Production by Homogeneous Catalysis: Alcohol Acceptorless Dehydrogenation. Hai Huang, Luning Tang, Yang Xi, Guangke He, Hongjun Zhu. Formation of Tertiary Amides and Dihydrogen by Dehydrogenative Coupling of Primary Alcohols with Secondary Amines Catalyzed by Ruthenium Bipyridine-Based Pincer Complexes. The process runs at a high substrate concentrate 100g/L and turned out to be technically feasible to perform successfully on a 40-kg scale. Shichao Zeng, Ji Liu, Sampson Anankanbil, Ming Chen, Zheng Guo, Joseph P. Adams, Radka Snajdrova. A. Watson, Aoife C. Maxwell, Jonathan M. J. Williams. α
Haolai Huang, Gaoqing Yuan, Xianwei Li, Huanfeng Jiang. iii
An efficient synthesis of amides from alcohols and azides catalyzed by a bifunctional catalyst Au/DNA under mild conditions. A polymer supported Cu(II) catalyst for oxidative amidation of benzyl alcohol and substituted amines in TBHP/H2O. Dehydrogenation as a Substrate-Activating Strategy in Homogeneous Transition-Metal Catalysis. N
Conditions which lead to the observed equilibrium are discussed. Ken-ichi Shimizu, Keiichiro Ohshima, Atsushi Satsuma. 4
N-Heterocyclic carbene-catalysed amidation of vinyl esters with aromatic amines. 3
2
Mingwen Zhu, Ken-ichi Fujita, and Ryohei Yamaguchi . Molecular catalysts for hydrogen production from alcohols. 1
Samim Sultana, Geetika Borah, Pradip K. Gogoi. Stereoretentive Copper(II)-Catalyzed Ritter Reactions of Secondary Cycloalkanols. Subhash Chandra Ghosh, Joyce S.Y. ) complex covalently anchoring a (2-iminomethyl)phenol moiety supported on HAp-encapsulated-α-Fe
Wanxiang Zhao, Hui Qian, Zigang Li, Jianwei Sun. Synthesis of amides through an oxidative amidation of tetrazoles with aldehydes under transition-metal-free conditions. The LibreTexts libraries are Powered by MindTouch® and are supported by the Department of Education Open Textbook Pilot Project, the UC Davis Office of the Provost, the UC Davis Library, the California State University Affordable Learning Solutions Program, and Merlot. Hosein Hamadi, Zohreh Zanjani, Mahtab Yadollahi. without permission from the American Chemical Society. Get article recommendations from ACS based on references in your Mendeley library. This limitation can be overcome by coupling the lipase-catalyzed enantioselective resolution with a racemization of the alcohol substrate, thus obtaining a dynamic kinetic resolution process. For example, acyloin acetate can be hydrolyzed with E > 300 leading to diol in excellent enantioselectivity (Scheme \(\PageIndex{8}\)). Iron(II) Pincer-Catalyzed Synthesis of Lactones and Lactams through a Versatile Dehydrogenative Domino Sequence. The reaction involves the same intermediates as the formation of imines and only the steps are reversed. General experimental procedure and compound characterization data. ii
Copper-Catalyzed Reductive
Visible light photoredox catalysed amidation of carboxylic acids with amines. Metal-catalyzed formal amidation of alkenes under CO-free condition. ) complexes of tetradentate bis(N-pyridylimidazolylidenyl)methane and their reactivities towards N- donors. Hall, Stephen P. Marsden, Ourida Saidi and Jonathan M. J. Williams . Ganesh Pandey, Suvajit Koley, Ranadeep Talukdar. Oxidations and Oxidative Couplings Catalyzed by Triazolylidene Ruthenium Complexes. Palladium-catalyzed carbonylation of quaternary ammonium halides to tertiary amides. Kristina Holzschneider, Andreas P. Häring, Alexander Haack, Daniel J. Corey, Thorsten Benter, and Stefan F. Kirsch . Francesca Dalu, Mariano A. Scorciapino, Claudio Cara, Alberto Luridiana, Anna Musinu, Mariano Casu, Francesco Secci, Carla Cannas. This is common for the carbon-carbon double and triple bonds which have the respective suffixes ene and yne. Copper-catalyzed one-pot oxidative amidation of alcohol to amide via C–H activation. Five-membered ring systems with one heteroatom: Synthetic routes, chemical reactivity, and biological properties of furan-carboxamide analogues. Liana Hie, Noah F. Fine Nathel, Xin Hong, Yun-Fang Yang, Kendall N. Houk, Neil K. Garg. Silica Gel-Mediated Amide Bond Formation: An Environmentally Benign Method for Liquid-Phase Synthesis and Cytotoxic Activities of Amides. Ji-Wei Wu, Ya-Dong Wu, Jian-Jun Dai, Hua-Jian Xu. Thatikonda Narendar Reddy, Adilson Beatriz, Vaidya Jayathirtha Rao, Dênis Pires de Lima. Triazolylidene-Iridium Complexes with a Pendant Pyridyl Group for Cooperative Metal-Ligand Induced Catalytic Dehydrogenation of Amines. Leng Leng Chng, Jinhua Yang, Jackie Y. Ying. We also acknowledge previous National Science Foundation support under grant numbers 1246120, 1525057, and 1413739. Shengwang Xia, Zhilei Jiang, Yuan Huang, Dawei Li, Yanfeng Cui, Yahong Li. Direct amide bond formation from carboxylic acids and amines using activated alumina balls as a new, convenient, clean, reusable and low cost heterogeneous catalyst. Renata Marcia de Figueiredo, Jean-Simon Suppo, and Jean-Marc Campagne . Primary aromatic amines form stable diazonium salts at zero degrees. Chul-Bae Kim, Hyunjong Jo, Bo-Kyoung Ahn, Chang Keun Kim and Kwangyong Park. Yuguang Wang, Zhongli Wu, Qin Li, Bingchun Zhu, Lei Yu. Formation of Nitriles, Carboxylic Acids, and Derivatives by Oxidation, Substitution, and Addition. Transamidation of primary amides with amines catalyzed by zirconocene dichloride. Nickel N-Heterocyclic Carbene Catalyst for Cross-Coupling of Neopentyl Arenesulfonates with Methyl and Primary Alkyl Grignard Reagents. Khushbu P. Patel, Eknath M. Gayakwad, Ganapati S. Shankarling. Aerobic Oxidations Catalyzed by Colloidal Nanogold. )–H bonds with fluoroaryl azides via Co(
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We use cookies to help provide and enhance our service and tailor content and ads. Well‐defined N‐heterocyclic carbene/ruthenium complexes for the alcohol amidation with amines: The dual role of cesium carbonate and improved activities applying an added ligand. Li-Mei Jin, Hongjian Lu, Yuan Cui, Christopher L. Lizardi, Thiago N. Arzua, Lukasz Wojtas, Xin Cui, X. Peter Zhang. Haloalkane reacts with aueous alkali or moist AgO to give corresponding alcohols. Technically, hydrolysis is a reaction with water. FeCl 3 -catalyzed selective acylation of amines with 1,3-diketones via C–C bond cleavage. Bu
Jean-Simon Suppo, Renata Marcia de Figueiredo, Jean-Marc Campagne. The reactions of a broad range of substrates have been well explored. Kenneth E. Schwieter and Jeffrey N. Johnston . Ya‐Fei Guo, Tian‐Lu Ren, Bao‐Hua Xu, Yao‐Feng Wang, Suo‐Jiang Zhang. Because aromatic diazonium salts are only stable at very low temperatures (zero degrees and below), warming these salts initiates decomposition into highly reactive cations. Efficient Synthesis of Amides and Esters from Alcohols under Aerobic Ambient Conditions Catalyzed by a Au/Mesoporous Al
The direct synthesis of N-alkylated amides via a tandem hydration/N-alkylation reaction from nitriles, aldoximes and alcohols. Tunable Dehydrogenative Amidation versus Amination Using a Single Ruthenium-NHC Catalyst. To make the hydrolysis as complete as possible, you would have to use an excess of water. from your Reading List will also remove any Andrew J.A. Discovery, Applications, and Catalytic Mechanisms of Shvo’s Catalyst. Stay connected with Kullabs. If the sulfonamide that forms dissolves in aqueous sodium hydroxide solution, it is a primary amine. Gao Wang, Qing-Ying Yu, Jian Wang, Shan Wang, Shan-Yong Chen, Xiao-Qi Yu. Harekrishna Sahoo, Sayan Mukherjee, Gowri Sankar Grandhi, Jayaraman Selvakumar, and Mahiuddin Baidya . with good enantioselectivity (Scheme \(\PageIndex{13}\)).